Gravimetrically characterizable common alkali reducing agents and ligand design of a new electron rich guanidinate

Efrain Maximiliano Castillo Noris, University of Texas at El Paso

Abstract

Synthesis, isolation and characterization of 12 new alkali arenides was performed by the addition of the chelating base 18-crown-6. Electrochemistry, UV-vis/NIR spectroscopy and XRD studies were performed. The incorporation of an imidazolin-2-iminato group to the background of a guanidinate showed that this kind of ligand is electronically flexible and metal dependent. It was found that is more electron donating than some previously reported guanidinates and ketimine guanidinates.^

Subject Area

Chemistry|Inorganic chemistry|Organic chemistry

Recommended Citation

Castillo Noris, Efrain Maximiliano, "Gravimetrically characterizable common alkali reducing agents and ligand design of a new electron rich guanidinate" (2016). ETD Collection for University of Texas, El Paso. AAI10151167.
http://digitalcommons.utep.edu/dissertations/AAI10151167

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