Processing of zirconium boride-zirconium carbide-zirconium disilicide ceramic by reactive metal penetration
The processing of ZrB2-ZrC-ZrxSi y composite by reactive metal penetration was investigated as a successor to the ZrB2-SiC composites for hypersonic vehicles application, which cannot be used for extended time at temperatures greater than 1600°C due to formation of SiO and CO gases. Zirconium (Zr), zirconium disilicide (ZrSi2), and boron carbide (B4C) were reacted in graphite crucibles for 60, 120, 180, and 240 minutes. Microscopy and x-ray diffraction (XRD) deduced the formation of a heterogeneous microstructure of ZrB 2-ZrC-ZrxSiy precipitates surrounded by a solidified Zr-Si melt. Unreacted boron carbide was observed in samples held at 1860°C for 60 minutes and 120 minutes, so thermodynamic equilibrium was not achieved. The reaction for the composite formation is as follows: [special characters omitted]The most consistent microstructures were seen on the samples heated for 180 minutes and 240 minutes, in which the free B4C completely decomposed to zirconium boride and carbide. Also, because of the closeness of the initial compositions of Zr and Si (12 wt% and 14 wt%) on the Zr-Si phase diagram, there was not much difference in the final phases obtained in both compositions.
Aerospace engineering|Mechanical engineering|Materials science
Maheswaraiah, Nischel B, "Processing of zirconium boride-zirconium carbide-zirconium disilicide ceramic by reactive metal penetration" (2010). ETD Collection for University of Texas, El Paso. AAI1477805.